Lithium batteries vs lead-acid (AGM/Gel)

What really differs: usable energy, lifespan, charge rates, safety and total cost of ownership — explained simply.

Lithium vs lead-acid batteries side by side
90–100%
Usable DoD (LiFePO₄)
2 500–6 000+
Cycles (LiFePO₄ @ 80–100% DoD)
300–800
Cycles (AGM/Gel @ 50% DoD)
TL;DR: Lithium (LiFePO₄) costs more upfront but delivers far more usable energy, higher cycle life and faster charging. Lead-acid can still work for low-budget, low-cycle backup, but expect larger banks and earlier replacement.

1) Key terms in 60 seconds

DoD Depth of Discharge — how much capacity you use. Cycle One full charge+discharge. C-rate Charge/discharge power relative to capacity. BMS Battery Management System — protects lithium cells.

2) Usable energy & lifespan

Battery typeUsable DoD (typ.)Cycle life (typ.)Notes
LiFePO₄ (lithium)90–100%2 500–6 000+Delivers most of nameplate energy with minimal degradation.
AGM / Gel (sealed lead-acid)50% (better: 30–50%)300–800Deep cycling shortens life quickly; keep DoD shallow.
Flooded lead-acid50% (better: 20–50%)300–600Maintenance required; ventilation needed.

Example: A “5 kWh” lithium gives ~4.8–5 kWh usable; a “5 kWh” lead-acid bank safely offers ~2.5 kWh (50% DoD). You’ll often need 2×–3× the lead-acid capacity to match lithium’s usable energy.

3) Charge/discharge power (C-rate)

  • Lithium (LiFePO₄): commonly 0.5–1C continuous, short peaks higher (check BMS/inverter limits).
  • Lead-acid: recommended 0.1–0.2C charging; higher rates cause heat, gas, and shorter life.

Practically: lithium can absorb solar faster on a good day and deliver higher peak loads without big voltage sag.

4) Temperature, safety & maintenance

  • Lithium (LiFePO₄): very stable chemistry; BMS protects against over/under-voltage & temp. Avoid charging < 0 °C unless battery is heated.
  • Lead-acid: tolerant to cold but heavy, gasses if overcharged (ventilation). Flooded cells need water top-ups.

5) Total cost of ownership (TCO)

Upfront, AGM/Gel is cheaper. Over 5–10 years of regular load-shedding cycles, lithium almost always wins on R/kWh delivered because it lasts longer and you buy less capacity for the same usable energy.

ScenarioLead-acid bankLithium bankComment
Essential loads ≈ 3 kWh/day ~6 kWh nameplate (50% DoD usable ≈ 3 kWh) — often replaced in 2–3 years ~3.6–4 kWh nameplate (usable ≈ 3.2–3.8 kWh) — lasts 5–10 years Lithium uses smaller bank and endures deep cycles better.
High peak appliances Voltage sag; large bank required for surge Handles surges better (check BMS limits) Lithium maintains voltage under load.

6) Charging profiles

  • Lithium: simpler CC/CV; charge to ~56.0–56.8 V for 48 V packs (brand-specific), no equalize/float required. Follow battery vendor profile.
  • Lead-acid: bulk/absorb/float; periodic equalize for flooded; temperature-compensated charging recommended.

7) When to choose which?

Choose Lithium (LiFePO₄) if you:
  • Cycle daily due to load-shedding or self-consumption.
  • Need compact, high-power, long-life storage.
  • Value lower R/kWh over the system’s life.
Lead-acid still ok if you:
  • Have very low cycle frequency (occasional backup only).
  • Have tight upfront budget and accept reduced lifespan.
  • Can allocate space/weight for a larger bank.

Quick sizing example

Goal: ~3 kWh usable per day.

  • Lithium: 3.6–4.0 kWh nameplate (90–100% DoD) ≈ 3.2–3.8 kWh usable.
  • Lead-acid: 6 kWh nameplate (50% DoD) ≈ 3 kWh usable.

Result: Lithium requires roughly half the nominal capacity for the same usable energy.

FAQ

Is LiFePO₄ safe?

Yes — LiFePO₄ is among the safest lithium chemistries. Use reputable brands and follow installation guidelines.

Can I mix old and new batteries?

Avoid mixing ages/capacities. In lithium banks, follow vendor rules for paralleling. In lead-acid, mixing causes imbalance and premature failure.

Do I need a BMS?

Lithium batteries include a BMS. Ensure CAN/RS485 comms with your inverter where supported for best performance and warranty compliance.


This guide is informational. Always follow manufacturer specifications and local electrical codes; use a qualified installer for compliance and CoC.